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Sodium hypophosphite

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[Autoignition]

230
[Fire Fighting]

Firefighters should wear full protective clothing and use self contained breathing apparauts. Use water as extinguishing media.
[Ingestion]

Seek medical attention if any symptoms develop.
[Inhalation]

Remove to fresh air.
[Skin]

Rinse abundantly with water.
[Eyes]

Rinse abundantly with water.
[Storage]

Keep containers closed when not in use. Store in a cool, dry place (protect from humidity, max storage temperature 25 deg C).
[Handling]

Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
[Ingestion]

Nausea, vomiting and diarrhea are possible if ingested.
[Inhalation]

Cough, tachypnea, and wheezing are common after inhalation.
[Skin]

Redness, swelling and pain may occur.
[Eyes]

Irritation.
[Personal Protection]

Wear protective gloves, chemical goggles and protective clothing. If working with product at elevated temepratures - also use repsiratory protection.
[Respirators]

Use NIOSH/MSHA approved respirator appropriate for exposure.
[Poison Class]

4
[Appearance]

White, crystalline solid. Odorless.
[Solubility in water]

Soluble.
[Melting Point]

100
[Density]

1.81 g/cm3 (20 C)
[Usage]

Pharmaceuticals, reducing agent in electrodeless nickel plating of plastics and metals, lab reagent, substitute for sodium nitrite in smoked meats.
[Product Name]

Sodium hypophosphite
[Synonyms]

Sodium phosphinate
[CAS]

"CASEN_7681-53-0.htm">7681-53-0
[Formula]

NaO2P
[Molecular Weight]

85.96
[EINECS]

231-669-9
[RTECS]

WB5950000
[RTECS Class]

Other
[Merck]

12,8775
[Beilstein/Gmelin]

11548 (G)
[Small spills/leaks]

Clean up personnel should wear full protective clothing - if material exposed to elevated temperatures also wear repsiratory protection. Collect spilled material into suitable labelled containers and hold for later disposal.
[Incompatibilities]

Keep away from oxidizing agents, magnesium, aluminum, acid halides, acid anhydrides, phosphorus halides, thionyl chlorides and carbonates.
[Stability]

Stable at normal temperatures and pressures.
[Decomposition]

Toxic fumes.
[Combustion Products]

Products of thermal decomposition include phosphorous hydrogen, phosphate/ phosphite, phosphoroustrioxide. Phosphorous hydrogen (Phosphan) is self igniting.