| [Flash Point] 105 | |
| [Autoignition] 450 | |
| [Fire Fighting] Extinguish using agent most appropriate for surrounding fire. | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. May polymerize explosively when involved in a fire. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Fire Potential] This chemical is flammable. | |
| [Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Ingestion] Seek medical assistance. | |
| [Inhalation] TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. Effects of contact or inhalation may be delayed. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
| [Inhalation] Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. | |
| [Skin] Contact with molten substance may cause severe burns to skin and eyes. See Inhalation. | |
| [Skin] Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical aid if symptoms occur. | |
| [Skin] Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. | |
| [Eyes] See Inhalation. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Eyes] Immediately flush with running water for at least 20 minutes. | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. | |
| [Ingestion] See Inhalation. | |
| [Inhalation] May cause severe allergic respiratory reaction. May cause respiratory tract irritation. Effects of inhalation may be delayed. | |
| [Skin] May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. If absorbed, may cause symptoms similar to those for ingestion. Effects of contact may be delayed. May cause contact dermatitis. | |
| [Eyes] Causes severe eye irritation. | |
| [Ingestion] May cause irritation of the digestive tract. May cause kidney damage. May cause methemoglobinemia, cyanosis, convulsions, and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. May be harmful if swallowed. | |
| [Hazards] When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 26/27/28 33 50 | |
| [EC Risk Phrase] R 45 20/21/22 | |
| [EC Safety Phrase] S 28 36/37 45 61 | |
| [EC Safety Phrase] S 53 45 | |
| [UN (DOT)] 2431 | |
| [UN (DOT)] 2811 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
| [Personal Protection] Wear appropriate protective gloves, clothing and goggles. | |
| [Respirators] Wear positive pressure self-contained breathing apparatus (SCBA). | |
| [Respirators] Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Exposure Effects] May cause cancer according to animal studies. | |
| [Exposure limit(s)] OSHA PEL: TWA 0.5 mg/m3 | |
| [Poison Class] 1* | |
| [Appearance] White, fused crystalline solid, characteristic amine odor. May darken on exposure to light and air. | |
| [Solubility in water] Soluble | |
| [Melting Point] 55 - 58 | |
| [Melting Point] 248 - 249 | |
| [Boiling Point] 243 | |
| [Boiling Point] 440 | |
| [Vapor Pressure] 0.03 (25 C) | |
| [Density] 1.2 g/cm3 (20 C) | |
| [pKa/pKb] 9.79 (pKb) | |
| [Partition Coefficient] .95 | |
| [Partition Coefficient] 3.78 | |
| [Heat Of Vaporization] 34.3 kJ/mol | |
| [Heat Of Combustion] -3571 kJ/mol | |
| [Usage] In the manufacture of azo dyes. | |
| [Vapor Density] 4.25 | |
| [Refractive Index] 1.5559 (60 C) | |
| [Product Name] 4-Methoxybenzeneamine | |
| [Synonyms] 1-Amino-4-methoxybenzene 4,4''-Diaminoterphenyl 4-[4-(4-Aminophenyl)phenyl]aniline 4-Methoxyaniline p,p'-Diaminoterphenyl | |
| [CAS] "CASEN_104-94-9.htm">104-94-9 | |
| [CAS] "CASEN_3365-85-3.htm">3365-85-3 | |
| [Formula] C18H16N2 | |
| [Formula] C7H9NO | |
| [Molecular Weight] 260.33999999999997 | |
| [Molecular Weight] 123.16 | |
| [EINECS] 203-254-2 | |
| [RTECS] BZ5450000 | |
| [RTECS Class] Tumorigen; Drug; Mutagen | |
| [Merck] 13,670 | |
| [Beilstein/Gmelin] 2120295 | |
| [Beilstein/Gmelin] 471556 | |
| [Beilstein Reference] 4-13-00-00480 | |
| [Beilstein Reference] 4-13-00-01015 | |
| [EC Index Number] 612-112-00-2 | |
| [EC Class] Very toxic; Danger of cumulative effects; Dangerous for the Environment | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Small spills/leaks] ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. | |
| [Disposal Code] 9 | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Incompatibilities] Strong oxidizing agents, acids, acid chlorides, acid anhydrides, chloroformates. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 2431 | |
| [UN Number] 2811 | |
| [Hazard Class] 6.1 | |
| [Packing Group] III | |
| [HS Code] 2922 22 00 |
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