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1-Chloromethyl naphthalene

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[Flash Point]

130
[Autoignition]

587
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4 C).
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.
[Ingestion]

Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
[Inhalation]

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

Causes skin irritation.
[Eyes]

Causes eye irritation. Lachrymator.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[EC Risk Phrase]

R 21/22 34
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

2811
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Clear, yellow liquid.
[Solubility in water]

Insoluble
[Melting Point]

32
[Boiling Point]

291
[Vapor Pressure]

3.4 (25 C)
[Density]

1.174 g/cm3 (20 C)
[Partition Coefficient]

3.72
[Heat Of Vaporization]

51.0 kJ/mol
[Vapor Density]

6.1
[Refractive Index]

1.62966 (20 C)
[Product Name]

1-Chloromethyl naphthalene
[Synonyms]

1-Naphthalenylmethyl chloride
1-Naphthylmethyl chloride
a-(Chloromethyl)naphthalene
[CAS]

"CASEN_86-52-2.htm">86-52-2
[Formula]

C11H9Cl
[Molecular Weight]

176.65
[EINECS]

201-678-2
[RTECS]

QJ2800000
[RTECS Class]

Other
[Beilstein/Gmelin]

636885
[Beilstein Reference]

4-05-00-01692
[EC Class]

harmful, corrosive
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.
[Disposal Code]

2
[Stability]

Stable at room temperature in closed containers under normal storage and handling conditions.
[Incompatibilities]

Strong oxidizing agents.
[Decomposition]

Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2811
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2903 69 90