| [Flash Point] 135 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Containers may explode when heated. Extinguishing media: Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
| [Skin] Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | |
| [Eyes] Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Storage under a nitrogen blanket has been recommended. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes. | |
| [Inhalation] Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. At high concentrations, isocyanates affect mucous membranes of the respiratory tract and may lead to fatal pulmonary edema. Exposure to low and often even unmeasurable isocyanate concentration results in sensitization. May cause systemic effects. Can produce delayed pulmonary edema. | |
| [Skin] Causes skin burns. Organic isocyanates can cause local irritation and allergic reactions. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color. | |
| [Eyes] Causes eye burns. Lachrymator. May cause chemical conjunctivitis and corneal damage. | |
| [Ingestion] May cause severe and permanent damage to the digestive tract. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 20/22 36/37/38 42 | |
| [EC Safety Phrase] S 23 26 36/37/39 45 | |
| [UN (DOT)] 1760 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Effects may be delayed. Chronic overexposure to isocyanates has been reported to cause lung damage, including decreased lung fuction, which may be permanent. | |
| [Poison Class] 2 | |
| [Appearance] Colorless liquid. Pungent odor. | |
| [Solubility in water] Insoluble | |
| [Melting Point] 36 | |
| [Boiling Point] 270 | |
| [Density] 1.18 g/cm3 | |
| [Vapor Density] 5.83 | |
| [Refractive Index] 1.63321 (20 C) | |
| [Product Name] 1-Isocyanatonaphthalene | |
| [Synonyms] 1-Naphthyl isocyanate Isocyanic acid, 1-naphthyl ester Naphthalen-1-ylisocyanate | |
| [CAS] "CASEN_86-84-0.htm">86-84-0 | |
| [Formula] C11H7NO | |
| [Molecular Weight] 169.18 | |
| [EINECS] 201-703-7 | |
| [Merck] 12,6497 | |
| [Beilstein/Gmelin] 742779 | |
| [Beilstein Reference] 4-12-00-03094 | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation. | |
| [Incompatibilities] Acids, alcohols, amines, heat, moisture, strong oxidizing agents, strong bases. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Decomposition] Hydrogen cyanide, carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1760 | |
| [Hazard Class] 8 | |
| [Packing Group] I; II; III |
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