| [Flash Point] >112 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. | |
| [Fire Potential] This material is probably combustible. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. | |
| [Skin] Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Storage] Store in a cool place in the original container and protect from sunlight. Store in a tightly closed container. | |
| [Handling] Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Wash clothing before reuse. | |
| [Inhalation] May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia. | |
| [Skin] May cause severe skin irritation. | |
| [Eyes] May cause severe eye irritation. May result in corneal injury. | |
| [Ingestion] Harmful if swallowed. May cause methemoglobinemia, cyanosis, convulsions, and death. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 20/21/22 33 | |
| [EC Safety Phrase] S 28 36/37 | |
| [UN (DOT)] 2811 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Exposure Effects] May cause liver and kidney damage. Prolonged exposure may cause anemia and methemoglobinemia, characterized by dizziness, drowsiness, headache, breath shortness, cyanosis, rapid heart rate and chocolate-brown colored blood. | |
| [Appearance] Colorless rhombic crystals, sweet odor. | |
| [Solubility in water] Insoluble | |
| [Melting Point] 62 - 64 | |
| [Boiling Point] 123.9 - 124.3 (14 torr) | |
| [Vapor Pressure] .2 | |
| [Density] 1.799 g/cm3 (20 C) | |
| [pKa/pKb] 9.98 (pKb) | |
| [Partition Coefficient] 2.26 | |
| [Usage] In prepn of azo dyes, condensed with formaldehyde in prepn of dihydroquinazolines. | |
| [Saturation Concentration] 224 ppm (0.02%) at 25 C (calculated) | |
| [Vapor Density] 5.9 | |
| [Refractive Index] 1.5835 (99.6 C) | |
| [Product Name] p-bromophenylamine | |
| [Synonyms] 4-Bromobenzenamine p-Bromophenylamine | |
| [CAS] "CASEN_106-40-1.htm">106-40-1 | |
| [Formula] C6H6BrN | |
| [Molecular Weight] 172.03 | |
| [EINECS] 203-393-9 | |
| [RTECS] BW9280000 | |
| [RTECS Class] Mutagen | |
| [Merck] 13,1388 | |
| [Beilstein/Gmelin] 742031 | |
| [Beilstein Reference] 4-12-00-01497 | |
| [EC Class] toxic, dangerous for the environment | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Disposal Code] 9 | |
| [Incompatibilities] Acids, acid chlorides, acid anhydrides, chloroformates, strong oxidizing agents, and sunlight. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide, nitrogen. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 2811 | |
| [Hazard Class] 6.1 | |
| [Packing Group] I; II; III | |
| [HS Code] 2921 42 10 |
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