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4-Bromobiphenyl

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[Flash Point]

142
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Fire Potential]

This chemical is combustible.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

May cause skin irritation. The toxicological properties of this material have not been fully investigated.
[Eyes]

May cause eye irritation. The toxicological properties of this material have not been fully investigated.
[Ingestion]

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
[Hazards]

Containers may explode when heated.
[EC Risk Phrase]

R 36/37/38
[EC Safety Phrase]

S 22 24/25
[UN (DOT)]

2315
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

The toxological properties of this substance have not been fully investigated.
[Appearance]

Colorless crystals.
[Solubility in water]

Insoluble
[Melting Point]

90 - 91
[Boiling Point]

310
[Vapor Pressure]

0.0011 (25 C)
[Density]

1.615 g/cm3
[Partition Coefficient]

5.44
[Heat Of Vaporization]

52.7 kJ/mol
[Heat Of Combustion]

-6132 kJ/mol
[Vapor Density]

8
[Product Name]

4-Bromobiphenyl
[Synonyms]

(4-Bromophenyl)benzene
1-bromo-4-phenylbenzene
4-Bromo-1,1'-biphenyl
p-Biphenylyl bromide
p-Phenylphenyl bromide
[CAS]

"CASEN_92-66-0.htm">92-66-0
[Formula]

C12H9Br
[Molecular Weight]

233.12
[EINECS]

202-176-6
[RTECS]

DV1750100
[RTECS Class]

Mutagen
[Beilstein/Gmelin]

1907453
[Beilstein Reference]

4-05-00-01819
[EC Class]

irritant
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
[Incompatibilities]

Oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2315
[Hazard Class]

9
[Packing Group]

II
[HS Code]

2903 69 90