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2-Chloroaniline

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[Flash Point]

105
[Autoignition]

> 500
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
[Upper exp. limit]

8.8
[Lower exp. limit]

1.5
[Fire Potential]

This chemical is combustible.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
[Skin]

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if symptoms occur.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Poison room locked.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with skin and eyes. Do not ingest or inhale.
[Inhalation]

May cause respiratory tract irritation. May cause effects similar to those described for ingestion.
[Skin]

Causes skin irritation. May be absorbed through the skin in harmful amounts. Produces acneiform eruptions.
[Eyes]

Causes eye irritation.
[Ingestion]

May cause irritation of the digestive tract. May cause methemoglobinemia, cyanosis, convulsions, and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. May cause skin eruptions and/or acne.
[Hazards]

Containers may explode when heated.
[EC Risk Phrase]

R 23/24/25 33 50/53
[EC Safety Phrase]

S 28 36/37/39 45 60 61
[UN (DOT)]

2019
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

May cause cancer according to animal studies.
[Exposure limit(s)]

NIOSH: Potential Occupational Carcinogen.
[Poison Class]

3
[Appearance]

Clear colorless to amber liquid, darkens on exposure to air, characteristic sweet amine odor.
[Solubility in water]

Insoluble
[Melting Point]

-3
[Boiling Point]

208
[Vapor Pressure]

19.5 (100 C)
[Density]

1.213 g/cm3 (20 C)
[pKa/pKb]

11.34 (pKb)
[Partition Coefficient]

1.9
[Heat Of Vaporization]

57.5 kJ/mol
[Heat Of Combustion]

-774 kJ/mol
[Usage]

Dye, pesticide, pigment, rubber chemicals intermediate.
[Saturation Concentration]

20 ppm (0.0020%) at 20 C (calculated)
[Vapor Density]

4.41
[Refractive Index]

1.5895 (20C)
[Product Name]

Fast yellow GC base
[Synonyms]

1-Amino-2-chlorobenzene
2-Chloroaminobenzene
Fast yellow GC base
o-Chloroaniline
[CAS]

"CASEN_95-51-2.htm">95-51-2
[Formula]

C6H6ClN
[Molecular Weight]

127.57
[EINECS]

202-426-4
[RTECS]

BX0525000
[RTECS Class]

Tumorigen; Mutagen
[Merck]

13,2136
[Beilstein/Gmelin]

606077
[Beilstein Reference]

4-12-00-01115
[EC Index Number]

612-010-00-8
[EC Class]

toxic, dangerous for the environment
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
[Disposal Code]

9
[Incompatibilities]

Acids, acid chlorides, acid anhydrides, strong oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
[Combustion Products]

Irritating and toxic hydrogen chloride and oxides of nitrogen may form in fires.
[UN Number]

2019
[Hazard Class]

6.1
[Packing Group]

II
[HS Code]

2921 42 10