[Flash Point] 118 | |
[Autoignition] 265 | |
[Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Extinguishing media: Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out. | |
[Upper exp. limit] 7.2 | |
[Lower exp. limit] 2.8 | |
[Fire Potential] This chemical is combustible. | |
[Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
[Inhalation] Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
[Skin] Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
[Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
[Storage] Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked. | |
[Handling] Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. | |
[Inhalation] May cause respiratory tract irritation. | |
[Skin] May be harmful if absorbed through the skin. Causes severe skin irritation and possible burns. | |
[Eyes] Causes severe eye irritation and possible burns. | |
[Ingestion] May cause irritation of the digestive tract. May be harmful if swallowed. | |
[Hazards] When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | |
[EC Risk Phrase] R 23/24/25 33 50/53 | |
[EC Safety Phrase] S 28 36/37 45 60 61 | |
[UN (DOT)] 1590 | |
[Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
[Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
[Exposure Effects] CNS effects include headache, dizziness, altered mental status, confusion (lethargy progressing coma), seizures, syncope; occur secondary to CNS hypoxia, usually with levels > 20%. | |
[Appearance] Light tan to dark gray crystals or brown solid. | |
[Solubility in water] < 1g/L | |
[Melting Point] 70 - 73 | |
[Boiling Point] 272 | |
[Vapor Pressure] 0.006 (25 C) | |
[Density] 1.567 g/cm3 (20 C) | |
[pKa/pKb] 11.10 (pKb) | |
[Partition Coefficient] 2.69 | |
[Heat Of Vaporization] 66.9 kJ/mol | |
[Heat Of Combustion] -725 kJ/mol | |
[Usage] Chemical intermediate for dyes and pesticides. | |
[Vapor Density] 5.59 | |
[Product Name] 3,4-Dichlorobenzenamine | |
[Synonyms] 1-Amino-3,4-dichlorobenzene 3,4-Dichlorobenzeneamine | |
[CAS] "CASEN_95-76-1.htm">95-76-1 | |
[Formula] C6H5Cl2N | |
[Molecular Weight] 162.02000000000001 | |
[EINECS] 202-448-4 | |
[RTECS] BX2625000 | |
[RTECS Class] Mutagen; Primary Irritant | |
[Merck] 13,3079 | |
[Beilstein/Gmelin] 636837 | |
[Beilstein Reference] 4-12-00-01257 | |
[EC Index Number] 612-010-00-8 | |
[EC Class] toxic, dangerous for the environment | |
[Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
[Disposal Code] 9 | |
[Stability] Stable under normal temperatures and pressures. | |
[Incompatibilities] Strong oxidizing agents, acids, acid anhydrides, acid chlorides. | |
[Decomposition] Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen. | |
[Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
[UN Number] 1590 | |
[Hazard Class] 6.1 | |
[Packing Group] II | |
[HS Code] 2921 42 10 |