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Allyl methacrylate

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[Flash Point]

33
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
[Fire Potential]

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
[Skin]

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep away from sources of ignition. Store in a tightly closed container. Refrigerator/flammables.
[Handling]

Wash thoroughly after handling. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use only in a chemical fume hood.
[Inhalation]

May cause allergic respiratory reaction. May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema.
[Skin]

Causes severe skin irritation. Harmful if absorbed through the skin.
[Eyes]

Causes severe eye irritation. Lachrymator. Lachrymator.
[Ingestion]

Harmful if swallowed. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea.
[Hazards]

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers.
[EC Risk Phrase]

R 10 21/22 23 50
[EC Safety Phrase]

S 36/37 45 61
[UN (DOT)]

1992
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause allergic respiratory reaction (asthma).
[Poison Class]

3
[Appearance]

Clear, colorless liquid with a pungent odor.
[Solubility in water]

4 g/L
[Melting Point]

-65
[Boiling Point]

144
[Vapor Pressure]

7 (25 C)
[Density]

0.934 g/cm3 (20 C)
[Partition Coefficient]

2.17
[Heat Of Vaporization]

37.6 kJ/mol
[Usage]

Cross-linking agent in contact lenses, in arable acrylic coatings.
[Refractive Index]

1.4356 (20 C)
[Product Name]

Allyl methacrylate
[Synonyms]

2-Propenoic acid, 2-methyl-, 2-propenyl ester
Methacrylic acid, allyl ester
Prop-2-enyl 2-methylprop-2-enoate
[CAS]

"CASEN_96-05-9.htm">96-05-9
[Formula]

C7H10O2
[Molecular Weight]

126.16
[EINECS]

202-473-0
[RTECS]

UD3483000
[RTECS Class]

Primary Irritant
[Beilstein/Gmelin]

1747406
[Beilstein Reference]

4-02-00-01529
[EC Index Number]

607-246-00-3
[EC Class]

Flammable; Toxic; Harmful; Dangerous for the Environment
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Wash area with soap and water. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.
[Incompatibilities]

Acids; bases; oxidizing agents; reducing agents; peroxides; heavy metals.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Carbon monoxide, carbon dioxide.
[Combustion Products]

Fire will produce irritating, corrosive and/or toxic gases.
[UN Number]

1992
[Hazard Class]

3
[Packing Group]

I; II; III
[HS Code]

2916 14 90