| [Flash Point] 38 | |
| [Autoignition] >450 | |
| [Fire Fighting] Small Fires: Dry chemical, carbon dioxide or water spray. Large Fires: Dry chemical, carbon dioxide, alcohol-resistant foam or water spray. | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. | |
| [Fire Potential] Combustible material: may burn but does not ignite readily. | |
| [Fire Potential] HIGHLY FLAMMABLE. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Ingestion] Seek medical assistance. | |
| [Inhalation] TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. Effects of contact or inhalation may be delayed. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. | |
| [Inhalation] Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Skin] Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. | |
| [Skin] Contact with molten substance may cause severe burns to skin and eyes. See Inhalation. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Eyes] Immediately flush with running water for at least 20 minutes. | |
| [Eyes] See Inhalation. | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. | |
| [Handling] Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Ingestion] See Inhalation. | |
| [Inhalation] Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. Can produce delayed pulmonary edema. May cause burning sensation in the chest. | |
| [Skin] Causes skin irritation. May cause irritation and dermatitis. May cause cyanosis of the extremities. | |
| [Eyes] Causes eye irritation. May cause chemical conjunctivitis and corneal damage. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of large amounts may cause CNS depression. Ingestion of large amounts of fluoride may include salivation, nausea, vomiting, abdominal pain, fever, labored breathing. Exposure to fluoride compounds can result in systemic toxic effects on the heart, liver, and kidneys. It may also deplete calcium levels in the body leading to hypocalcemia and death. Fluoride can reduce calcium levels leading to fatal hypocalcemia. | |
| [Hazards] Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | |
| [Hazards] When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | |
| [EC Risk Phrase] R 10 36/37/38 | |
| [EC Risk Phrase] R 34 | |
| [EC Safety Phrase] S 26 36 | |
| [EC Safety Phrase] S 26 36/37/39 45 | |
| [UN (DOT)] 2234 | |
| [UN (DOT)] 3265 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Personal Protection] Wear appropriate protective gloves, clothing and goggles. | |
| [Respirators] Wear positive pressure self-contained breathing apparatus (SCBA). | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Chronic inhalation and ingestion may cause fluorosis with skeletal abnormalities. Effects may be delayed. Chronic exposure to fluoride compounds may cause systemic toxicity. | |
| [Appearance] Clear, colorless liquid with a fish-like odor. | |
| [Solubility in water] Insoluble | |
| [Melting Point] -56 | |
| [Melting Point] 58.5 | |
| [Boiling Point] 138 | |
| [Boiling Point] 29 (0.04 torr) | |
| [Vapor Pressure] 6.5 (21 C) | |
| [Density] 1.7014 g/cm3 (20 C) | |
| [Density] 1.331 g/cm3 (20 C) | |
| [Vapor Density] 6.23 | |
| [Refractive Index] 1.4438 (25 C) | |
| [Refractive Index] 1.50 (20 C) | |
| [Product Name] 3-Chlorobenzotrifluoride | |
| [Synonyms] 1-Chloro-3-(trifluoromethyl)benzene 3-Chloro-alpha,alpha,alpha-trifluorotoluene Butanoic acid, 2,3-dibromo-, ethyl ester Ethyl 2,3-dibromobutanoate m-Chlorobenzotrifluoride | |
| [CAS] "CASEN_609-11-0.htm">609-11-0 | |
| [CAS] "CASEN_98-15-7.htm">98-15-7 | |
| [Formula] C6H10Br2O2 | |
| [Formula] C7H4ClF3 | |
| [Molecular Weight] 180.56 | |
| [Molecular Weight] 273.95 | |
| [EINECS] 202-642-9 | |
| [EINECS] 210-177-8 | |
| [Beilstein/Gmelin] 1722550 | |
| [Beilstein/Gmelin] 510215 | |
| [Beilstein Reference] 3-02-00-00634 | |
| [Beilstein Reference] 4-05-00-00814 | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. | |
| [Small spills/leaks] ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. | |
| [Incompatibilities] Oxidizing agents. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Decomposition] Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride. | |
| [Combustion Products] During afire, irritating and highly toxic gases may be generated by thermaldecomposition or combustion. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 2234 | |
| [UN Number] 3265 | |
| [Hazard Class] 3 | |
| [Packing Group] III |
Print