[Flash Point] 114 | |
[Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Do NOT use water directly on fire. Use carbon dioxide or dry chemical. | |
[Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
[Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
[Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | |
[Skin] Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | |
[Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
[Storage] Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Corrosives area. Do not store in metal containers. | |
[Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. | |
[Ingestion] Causes gastrointestinal tract burns. | |
[Inhalation] May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. | |
[Skin] Contact with skin causes irritation and possible burns, especially if the skin is wet or moist. Vesicant. | |
[Eyes] May cause eye injury. Lachrymator. Causes eye irritation and burns. | |
[Hazards] Contact with metals may evolve flammable hydrogen gas. | |
[EC Risk Phrase] R 34 37 | |
[EC Safety Phrase] S 26 28 36/37/39 45 | |
[UN (DOT)] 1759 | |
[Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
[Respirators] Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. | |
[Poison Class] 2 | |
[Appearance] A white to gray powdered solid with a distinctive odor. | |
[Solubility in water] Insoluble | |
[Melting Point] 67 | |
[Boiling Point] 265 | |
[Vapor Pressure] 0.015 (25 C) | |
[Density] 1.49 g/cm3 | |
[Partition Coefficient] 2.45 | |
[Heat Of Vaporization] 48.3 kJ/mol | |
[Usage] Organic synthesis. | |
[Vapor Density] 1.33 | |
[Product Name] 4-Toluene sulfochloride | |
[Synonyms] 4-Methylbenzenesulfonyl chloride p-Tolylsulfonyl chloride p-Tosyl chloride | |
[CAS] "CASEN_98-59-9.htm">98-59-9 | |
[Formula] C7H7ClO2S | |
[Molecular Weight] 190.65 | |
[EINECS] 202-684-8 | |
[Merck] 12,9672 | |
[Beilstein/Gmelin] 607898 | |
[Beilstein Reference] 4-11-00-00375 | |
[EC Class] corrosive | |
[Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. | |
[Disposal Code] 11 | |
[Stability] Stable under normal temperatures and pressures. | |
[Incompatibilities] Strong oxidizers. Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. | |
[Decomposition] Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide. | |
[Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
[UN Number] 1759 | |
[Hazard Class] 8 | |
[Packing Group] I; II; III | |
[HS Code] 2904 90 20 |