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3-Nitrotoluene

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[Flash Point]

102
[Autoignition]

440
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. Do NOT use straight streams of water. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use water spray, fog or regular foam.
[Upper exp. limit]

7.6
[Lower exp. limit]

1.6
[Fire Potential]

Moderately flammable. Flammable liquid.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation.
[Inhalation]

May be fatal if inhaled. Aspiration may cause respiratory swelling and pneumonitis. Aspiration may lead to pulmonary edema. Effects of inhalation may be delayed.
[Skin]

May cause skin irritation. Effects of contact may be delayed.
[Eyes]

May cause eye irritation.
[Ingestion]

Aspiration hazard. May cause digestive tract disturbances. May be harmful if swallowed.
[Hazards]

Containers may explode when heated.
[EC Risk Phrase]

R 23/24/25 33 51/53
[EC Safety Phrase]

S 28 37 45 61
[UN (DOT)]

1664
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

CNS effects include headache, dizziness, altered mental status, confusion (lethargy progressing coma), seizures, syncope; occur secondary to CNS hypoxia, usually with levels > 20%.
[Exposure limit(s)]

NIOSH REL: TWA 2 ppm (11 mg/m3) [skin] OSHA PEL: TWA 5 ppm (30 mg/m3) [skin] IDLH 200 ppm
[Poison Class]

3
[Appearance]

Yellow liquid, weak aromatic odor.
[Solubility in water]

500 mg/L
[Melting Point]

15.5
[Boiling Point]

230
[Vapor Pressure]

0.14 (25 C)
[Density]

1.1571 g/cm3 (20 C)
[Partition Coefficient]

2.45
[Heat Of Vaporization]

44.2 kJ/mol
[Heat Of Combustion]

-3578 kJ/mol
[Usage]

Manufacture of dyes, toluidines, nitrobenzoic acids. Nitrotoluene.
[Vapor Density]

4.73
[Saturation Concentration]

130 ppm (0.01%) at 20 C (calculated)
[Odor threshold]

1.74 ppm
[Refractive Index]

1.5466 (20C)
[Product Name]

m-Nitrophenylmethane
[Synonyms]

1-Methyl-3-nitrobenzene
3-Nitrotoluene
[CAS]

"CASEN_99-08-1.htm">99-08-1
[Formula]

C7H7NO2
[Molecular Weight]

137.13999999999999
[EINECS]

202-728-6
[RTECS]

XT2975000
[RTECS Class]

Tumorigen; Mutagen; Reproductive Effector
[Merck]

12,6748
[Beilstein/Gmelin]

1906910
[Beilstein Reference]

4-05-00-00847
[EC Class]

toxic
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
[Disposal Code]

9
[Incompatibilities]

Oxidizing agents
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
[Combustion Products]

Emits toxic fumes of oxides of nitrogen.
[UN Number]

1664
[Hazard Class]

6.1
[Packing Group]

II
[HS Code]

2904 20 00