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2,4'-Dibromoacetophenone

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[Flash Point]

114
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
[Skin]

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
[Eyes]

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
[Storage]

Store in a cool, dry place. Keep container closed when not in use. Store in a tightly closed container. Corrosives area.
[Handling]

Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Use with adequate ventilation. Use only in a chemical fume hood. Discard contaminated shoes.
[Ingestion]

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
[Inhalation]

Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
[Skin]

Causes skin burns.
[Eyes]

Causes eye burns. Lachrymator.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[EC Risk Phrase]

R 34 36/37
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

2928
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Slightly yellow solid.
[Solubility in water]

Sparingly soluble
[Melting Point]

107 - 108
[Boiling Point]

310
[Vapor Pressure]

0.0006 (25 C)
[Partition Coefficient]

2.96
[Heat Of Vaporization]

55.1 kJ/mol
[Usage]

Identification of carboxylic acids.
[Vapor Density]

9.6
[Product Name]

2,4'-Dibromoacetophenone
[Synonyms]

4-Bromo(bromoacetyl)benzene
Acetophenone, 2,4'-dibromo
Bromomethyl-4-bromophenyl-ketone
Bromomethyl-p-bromophenyl-ketone
p-Bromophenacyl bromide
[CAS]

"CASEN_99-73-0.htm">99-73-0
[Formula]

C8H6Br2O
[Molecular Weight]

277.95
[EINECS]

202-783-6
[RTECS]

AM6950000
[RTECS Class]

Other
[Merck]

13,1412
[Beilstein/Gmelin]

607604
[Beilstein Reference]

4-07-00-00652
[EC Class]

corrosive
[Small spills/leaks]

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
[Disposal Code]

3
[Stability]

Stable at room temperature in closed containers under normal storage and handling conditions.
[Incompatibilities]

Strong oxidizing agents.
[Decomposition]

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2928
[Hazard Class]

6.1
[Packing Group]

I; II
[HS Code]

2914 70 90