| [Flash Point] -8 | |
| [Flash Point] 90 | |
| [Autoignition] 426 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustible Liquid. Can form explosive mixtures at temperatures above the flashpoint. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam. | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Do NOT use water directly on fire. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. Use water only in flooding quantities as fog. | |
| [Upper exp. limit] 14 | |
| [Lower exp. limit] 2.6 | |
| [Fire Potential] Extremely flammable liquid. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | |
| [Inhalation] Causes chemical burns to the respiratory tract. | |
| [Skin] Causes skin burns. | |
| [Skin] Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Skin] Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. | |
| [Eyes] Causes eye burns. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. SPEEDY ACTION IS CRITICAL! | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Keep away from polymerization catalysts. Storage for long periods is not recommended. | |
| [Storage] Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Corrosives area. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Wash clothing before reuse. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Handling] Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. | |
| [Ingestion] Causes gastrointestinal tract burns. | |
| [Inhalation] May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Vapors may cause dizziness or suffocation. | |
| [Skin] May cause mild skin irritation. Material evaporates quickly from open skin. However, it may cause burns if trapped under clothing. | |
| [Eyes] Contact with eyes may cause severe irritation, and possible eye burns. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. | |
| [Hazards] When heated to decomposition, it burns and emits acrid fumes. Highly dangerous when exposed to heat, flames or oxidizers; explosion hazard with strong acids and strong oxidizers. Incompatible with alumina, oxidizing materials, 2-aminoethanol, chlorosulfonic acid; ethyleneimine; 36% hydrochloric acid; 48.7% hydrofluoric acid; 70% nitric acid; oleum; 96% sulfuric acid; ethylene diamine; peroxides and silica gel. Avoid light or any polymerizing initiator. Hazardous polymerization can be initiated by organic and inorganic peroxides; azo compounds; redox systems (including organometallic components); light; and high energy radiation. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 11 40 | |
| [EC Risk Phrase] R 34 | |
| [EC Safety Phrase] S 26 36/37/39 45 | |
| [EC Safety Phrase] S 9 16 33 | |
| [UN (DOT)] 1301 | |
| [UN (DOT)] 1760 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Possible cancer hazard based on tests with laboratory animals. Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration. | |
| [Exposure limit(s)] TLV: 10,A3 ppm; 35,A3 mg/m3 (as TWA); 15,A3 ppm; 53,A3mg/m3 (as STEL) (ACGIH 1994-1995). NIOSH REL: C 4 ppm (15 mg/m3) 15-minute | |
| [Poison Class] 4 | |
| [Appearance] Clear yellow brown liquid. | |
| [Appearance] Clear, colorless liquid with an initial pleasant, fruity odor, which quickly becomes sharp and irritating. | |
| [Solubility in water] Insoluble | |
| [Solubility in water] Very soluble | |
| [Melting Point] -100 | |
| [Melting Point] 81 | |
| [Boiling Point] 72.3 | |
| [Boiling Point] 197 | |
| [Vapor Pressure] 100 (25 C) | |
| [Vapor Pressure] 0.75 (20 C) | |
| [Density] 0.932 g/cm3 (20 C) | |
| [Density] 1.0583 g/cm3 (20 C) | |
| [pKa/pKb] 5.30 (pKb) | |
| [Partition Coefficient] -.4 | |
| [Partition Coefficient] .73 | |
| [Heat Of Vaporization] 34.4 kJ/mol | |
| [Heat Of Vaporization] 43.9 kJ/mol | |
| [Heat Of Combustion] -1931 kJ/mol | |
| [Usage] In polymerized form for plastic masses, films, and lacquers. | |
| [Vapor Density] 3 | |
| [Saturation Concentration] 10.9% at 20 C | |
| [Odor threshold] 0.12 ppm | |
| [Refractive Index] 1.39258 (20 C) | |
| [Refractive Index] 1.5465 (20 C) | |
| [Product Name] Vinyl acetate | |
| [Synonyms] (2-Pyridyl)methanamine (2-Pyridylmethyl)amine 1-Acetoxyethylene 2-Picolylamine 2-Pyridinemethanamine 2-Pyridinylmethylamine a-(Aminomethyl)pyridine Acetic acid, ethenyl ester Acetic acid, vinyl ester Ethenyl acetate Vinyl ethanoate | |
| [CAS] "CASEN_108-05-4.htm">108-05-4 | |
| [CAS] "CASEN_3731-51-9.htm">3731-51-9 | |
| [Formula] C4H6O2 | |
| [Formula] C6H8N2 | |
| [Molecular Weight] 86.09 | |
| [Molecular Weight] 108.14 | |
| [EINECS] 203-545-4 | |
| [EINECS] 223-090-5 | |
| [RTECS] AK0875000 | |
| [RTECS] US1840000 | |
| [RTECS Class] Other | |
| [RTECS Class] Tumorigen; Mutagen; Reproductive Effector; Primary Irritant | |
| [Merck] 12,10130 | |
| [Beilstein/Gmelin] 1209327 | |
| [Beilstein/Gmelin] 108054 | |
| [Beilstein Reference] 4-02-00-00176 | |
| [Beilstein Reference] 5-22-09-00232 | |
| [EC Index Number] 607-023-00-0 | |
| [EC Class] corrosive | |
| [EC Class] Highly flammable | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. | |
| [Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. | |
| [Disposal Code] 1 | |
| [Disposal Code] 5 | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Stability] Stable under normal temperatures and pressures. May polymerize. | |
| [Incompatibilities] Strong acids, ammonia, nitric acid, peroxides, sulfuric acid, alliphatic amines, ozone, oleum, hydrochloric acid, hydrofluoric acid, ethyleneimine, ethylene diamine, nonoxidizing mineral acids, alkanolamines. | |
| [Incompatibilities] Strong oxidizing agents. | |
| [Decomposition] Carbon monoxide, carbon dioxide. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, carbon dioxide. | |
| [Combustion Products] Combustion may produce irritants and toxic gases. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1301 | |
| [UN Number] 1760 | |
| [Hazard Class] 3 | |
| [Hazard Class] 8 | |
| [Packing Group] I; II; III | |
| [Packing Group] II | |
| [HS Code] 2915 32 00 | |
| [HS Code] 2933 39 99 |
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