Triphenyl bismuth (603-33-8)

The Triphenylbismuthine, with its CAS registry number 603-33-8, is a kind of white to off-white crystalline powder. For being sensitive to moisture and insoluble in water, its product categories are including blocks; BuildingBlocks; Organometallics.

The physical properties of this chemical are as below: (1)#H bond acceptors: 0 ; (2)#H bond donors: 0 ; (3)#Freely Rotating Bonds: 3 ; (4)Polar Surface Area: 0; (5)Exact Mass: 440.097758; (6)MonoIsotopic Mass: 440.097758; (7)Heavy Atom Count: 19; (8)Complexity: 202; (9)Covalently-Bonded Unit Count: 1.

Use of this chemical is below: Triphenylbismuthine could react with piperidine to produce 1-phenyl-piperidine with the catalytic agent of Cu(OAc)₂ and the solvent of CH₂Cl₂. And in this reaction, the reaction time is 18 hour(s) and the yield is 56 % in the ambient temperature.

When you are dealing with this chemical, you should be careful. For being a kind of harmful chemical which may cause damage to health, it is dangerous to our body if by inhalation, in contact with skin and if swallowed. Therefore, you should wear suitable protective clothing and gloves and then avoid contact with skin and eyes.

In addition, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: C1=CC=C(C=C1)[Bi](C2=CC=CC=C2)C3=CC=CC=C3
(2)InChI: InChI=1S/3C6H5.Bi/c3*1-2-4-6-5-3-1;/h3*1-5H;
(3)InChIKey: ZHXAZZQXWJJBHA-UHFFFAOYSA-N 

Below are the toxicity information of this chemical:

Reported in EPA TSCA Inventory.