| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Fire Potential] This material is probably combustible. | |
| [Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. | |
| [Skin] Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Handling] Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. The anhydrous form of this substance is harmful if swallowed. | |
| [Inhalation] May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. | |
| [Skin] May cause skin irritation. The toxicological properties of this material have not been fully investigated. | |
| [Eyes] Contact may cause transient eye irritation. The toxicological properties of this material have not been fully investigated. | |
| [EC Risk Phrase] R 25 50/53 | |
| [EC Safety Phrase] S 45 60 61 | |
| [UN (DOT)] 2811 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Appearance] White crystalline powder or solid. Slight odor. | |
| [Solubility in water] 3.3 g/L (20 C) | |
| [Melting Point] 93 - 94 | |
| [Density] 1.259 g/cm3 | |
| [Usage] Used as a bidentate ligand in coordination chemistry. | |
| [Vapor Density] 6.2 | |
| [Product Name] 1,10-Phenanthroline hydrate | |
| [Synonyms] 4,5-Phenanthroline monohydrate o-Phenanthroline monohydrate | |
| [CAS] "CASEN_5144-89-8.htm">5144-89-8 | |
| [Formula] C12H10N2O | |
| [Molecular Weight] 198.24 | |
| [EINECS] 200-629-2 | |
| [RTECS] SF8437000 | |
| [RTECS Class] Mutagen | |
| [Merck] 12,7356 | |
| [Beilstein/Gmelin] 4008096 | |
| [Beilstein Reference] 5-23-08-00419 | |
| [EC Index Number] 613-092-00-8 | |
| [EC Class] toxic, dangerous for the environment | |
| [Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. | |
| [Disposal Code] 9 | |
| [Incompatibilities] Oxidizing agents. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. | |
| [UN Number] 2811 | |
| [HS Code] 2933 99 90 |
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