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3-Chlorobenzyl bromide

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[Flash Point]

104
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Fire Potential]

Non-Combustible
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. Keep from contact with moist air and steam.
[Ingestion]

Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
[Inhalation]

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

Causes skin irritation. The toxicological properties of this material have not been fully investigated.
[Eyes]

Causes eye irritation. Lachrymator.
[EC Risk Phrase]

R 34
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

3276
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Light yellow liquid.
[Solubility in water]

Insoluble
[Melting Point]

17.5
[Boiling Point]

238
[Vapor Pressure]

0.07 (25 C)
[Density]

1.5652 g/cm3 (25 C)
[Partition Coefficient]

3.51
[Heat Of Vaporization]

45.5 kJ/mol
[Vapor Density]

7.1
[Refractive Index]

1.59 (20 C)
[Product Name]

1-(Bromomethyl)-3-chlorobenzene
[Synonyms]

1-(Bromomethyl)-3-chlorobenzene
alpha-Bromo-3-chlorotoluene
alpha-Bromo-m-chlorotoluene
[CAS]

"CASEN_766-80-3.htm">766-80-3
[Formula]

C7H6BrCl
[Molecular Weight]

205.48
[EINECS]

212-171-0
[Beilstein/Gmelin]

636504
[Beilstein Reference]

4-05-00-00833
[Small spills/leaks]

Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Provide ventilation.
[Incompatibilities]

Oxidizing agents.
[Stability]

Stable at room temperature in closed containers under normal storage and handling conditions.
[Decomposition]

Chlorine, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, chloride fumes, bromine fumes, bromine.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

3276
[Hazard Class]

6.1
[Packing Group]

I; II; III