| [Flash Point] 2 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use foam, dry chemical, or carbon dioxide. | |
| [Fire Potential] HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | |
| [Skin] Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Destroy contaminated shoes. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Storage] Keep away from heat, sparks, and flame. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. | |
| [Handling] Wash thoroughly after handling. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Inhalation] May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation. Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. | |
| [Skin] Causes skin burns. | |
| [Eyes] Causes eye burns. Lachrymator. | |
| [Ingestion] Causes gastrointestinal tract burns. | |
| [Hazards] Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | |
| [EC Risk Phrase] R 11 36/37/38 | |
| [EC Safety Phrase] S 16 26 36/37/39 | |
| [UN (DOT)] 1862 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Exposure Effects] The toxological properties of this substance have not been fully investigated. | |
| [Poison Class] 4 | |
| [Appearance] Clear, colorless liquid with a pungent odor. | |
| [Solubility in water] Insoluble | |
| [Melting Point] -79 | |
| [Boiling Point] 143 | |
| [Density] 0.9208 g/cm3 (20 C) | |
| [Partition Coefficient] 1.35 | |
| [Vapor Density] 3.93 | |
| [Refractive Index] 1.4245 (24 C) | |
| [Product Name] Ethyl crotonate | |
| [Synonyms] 2-Butenoic acid, ethyl ester, (2E)- Ethyl (E)-2-butenoate trans-2-Butenoic acid ethyl ester | |
| [CAS] "CASEN_623-70-1.htm">623-70-1 | |
| [Formula] C6H10O2 | |
| [Molecular Weight] 114.15 | |
| [EINECS] 210-808-7 | |
| [RTECS] GQ3500000 | |
| [RTECS Class] Primary Irritant | |
| [Merck] 13,2625 | |
| [Beilstein/Gmelin] 635834 | |
| [Beilstein Reference] 4-02-00-01500 | |
| [EC Class] highly flammable | |
| [Small spills/leaks] Wash area with soap and water. Clean up spills immediately, using the appropriate protective equipment. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. | |
| [Disposal Code] 1 | |
| [Incompatibilities] Oxidizing agents. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Decomposition] Carbon monoxide, carbon dioxide, acrid smoke and fumes. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1862 | |
| [Hazard Class] 3 | |
| [Packing Group] II | |
| [HS Code] 2916 19 80 |
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