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3,4-Dichlorophenol

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[Flash Point]

109
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
[Fire Potential]

This material is probably combustible.
[Ingestion]

Get medical aid. Wash mouth out with water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Store in a cool, dry place. Store in a tightly closed container.
[Handling]

Wash thoroughly after handling. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
[Inhalation]

May cause respiratory tract irritation. Exposure produces central nervous system depression. May be harmful if inhaled. May cause liver damage.
[Skin]

Causes skin irritation. May be harmful if absorbed through the skin.
[Eyes]

Causes eye irritation.
[Ingestion]

Harmful if swallowed. May cause irritation of the digestive tract. May cause burning sensations, coughing, wheezing, laryngitis, shortness of breath and headache.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
[EC Risk Phrase]

R 21/22 36/37/38
[EC Safety Phrase]

S 24 26 36/37/39
[UN (DOT)]

2020
[Personal Protection]

Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

Prolonged exposure can cause damage to the eyes, severe irritation or burns.
[Appearance]

Needles (from benzene, petroleum ether) or light brown and yellow crystals.
[Solubility in water]

Insoluble
[Melting Point]

66 - 68
[Boiling Point]

247
[Vapor Pressure]

0.017 (25 C)
[Density]

1.6 g/cm3
[pKa/pKb]

8.55 (pKa)
[Partition Coefficient]

3.33
[Heat Of Vaporization]

50.4 kJ/mol
[Heat Of Combustion]

-2749 kJ/mol
[Usage]

Chemical intermediate for 2-chloro-1,4-dihydroxyanthraquinone & 2,3,4-trichlorophenol.
[Vapor Density]

5.6
[Odor threshold]

100 ug/L in water
[Product Name]

3,4-Dichlorophenol
[Synonyms]

4,5-Dichlorophenol
Phenol, 3,4-dichloro-
[CAS]

"CASEN_95-77-2.htm">95-77-2
[Formula]

C6H4Cl2O
[Molecular Weight]

163
[EINECS]

202-450-5
[RTECS]

SK8800000
[RTECS Class]

Other
[Beilstein/Gmelin]

1907693
[Beilstein Reference]

4-06-00-00952
[EC Class]

irritant
[Small spills/leaks]

Vacuum or sweep up material and place into a suitable disposal container.
[Disposal Code]

3
[Incompatibilities]

Oxidizing agents, acid chlorides, acid anhydrides.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Hydrogen chloride, carbon monoxide, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2020
[Hazard Class]

6.1
[Packing Group]

III
[HS Code]

2908 10 00