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3'-Chloroacetophenone

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[Flash Point]

105
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Fire Potential]

May burn but not ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.).
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
[Ingestion]

Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

Causes skin irritation. The toxicological properties of this material have not been fully investigated.
[Eyes]

Causes eye irritation. Lachrymator.
[Hazards]

Substance will react with water (some violently), releasing corrosive and/or toxic gases.
[EC Risk Phrase]

R 36/38
[EC Safety Phrase]

S 26 36
[UN (DOT)]

1754
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Clear, colorless liquid.
[Solubility in water]

Insoluble
[Boiling Point]

241
[Density]

1.213 g/cm3 (0 C)
[Vapor Density]

5.3
[Refractive Index]

1.5494 (20 C)
[Product Name]

3'-Chloroacetophenone
[Synonyms]

1-Acetyl-3-chlorobenzene
3'-Chloroacetophenone
3-Chlorophenyl methyl ketone
m-Chloroacetophenone
Methyl 3-chlorophenyl ketone
[CAS]

"CASEN_99-02-5.htm">99-02-5
[Formula]

C8H7ClO
[Molecular Weight]

154.6
[EINECS]

202-721-8
[Beilstein/Gmelin]

636318
[Beilstein Reference]

4-07-00-00638
[EC Class]

irritant
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.
[Incompatibilities]

Oxidizing agents.
[Stability]

Stable at room temperature in closed containers under normal storage and handling conditions.
[Decomposition]

Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[Combustion Products]

Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air.
[UN Number]

1754
[Hazard Class]

8
[Packing Group]

I
[HS Code]

2914 70 90