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3-Aminoacetophenone

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[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep containers tightly closed. Store in a cool, dry area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not breathe dust.
[Inhalation]

May cause cyanosis, characterized by bluish-colored skin. Causes irritation of the mucous membrane and upper respiratory tract.
[Skin]

Causes mild skin irritation. May be harmful if absorbed through the skin.
[Eyes]

May cause eye irritation. May cause chemical conjunctivitis.
[Ingestion]

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. May form methemoglobin which in sufficient concentration causes cyanosis.
[EC Risk Phrase]

R 22
[EC Safety Phrase]

S 28 36/37
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Exposure Effects]

Absorption into the body leads to the formation of methemoglobin which in sufficient concentrations causes cyanosis. Effects may be delayed.
[Poison Class]

4
[Appearance]

Brown flakes.
[Solubility in water]

Slightly soluble
[Melting Point]

94 - 97
[Boiling Point]

290
[Product Name]

m-Aminoacetophenone
[Synonyms]

1-(3-Aminophenyl)ethanone
3-Acetylaniline
m-Acetylaniline
m-Aminoacetophenone
[CAS]

"CASEN_99-03-6.htm">99-03-6
[Formula]

C8H9NO
[Molecular Weight]

135.16999999999999
[EINECS]

202-722-3
[RTECS]

AM5800000
[RTECS Class]

Mutagen; Primary Irritant
[Merck]

13,412
[Beilstein/Gmelin]

386009
[Beilstein Reference]

4-14-00-00096
[EC Class]

harmful
[Small spills/leaks]

Wash area with soap and water. Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
[Disposal Code]

3
[Stability]

Stable under normal temperatures and pressures. Partly volatile in steam.
[Incompatibilities]

Strong oxidizing agents, strong reducing agents, acids, acid anhydrides, chloroformates, acid chlorides.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide.
[HS Code]

2922 39 00